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Comparison of the extraction efficiencies of four different solvents used in trace metal digestion of selected soils within Abakaliki, Nigeria
OMAKA, NDUKAKU OMAKA; OFFOR, IFEANYI FRANCIS; CHUKWU, EBUBE REBECCA & EWUZIE, UGOCHUKWU
Abstract
Soil pollution by trace metals is one of the major global environmental
challenges facing us today. Extraction methods are key to predicting plant uptake of trace
metals from soil. This work seeks to compare the extraction efficiencies of EDTA, DTPA,
HNO3/HClO4 and HCl/HNO3 used in the digestion of soil samples collected from 11 different
locations (7 farmlands, 2 waste dumpsites and 2 sections of a mechanic workshop) within
Abakaliki metropolis, between August and September 2007. Concentrations of 7 selected
trace metals (Pb, Zn, Mn, Ni, Cd, Cu and Fe) were determined in the digested soil samples
using atomic absorption spectrophotometer. The concentrations (mg/kg) range, irrespective of
sampling sites were: Pb (2.85-43.07; 1.42-11.49; 3.83-131.90; 1.98-184.12), Zn (0.02-3.98;
0.01-0.79; 2.25-13.22; 0.15-39.45), Mn (1.33-78.83; 0.38-14.85; 1.02-66.24; 0.84-104.39), Ni
(1.15-14.10; 0.07-2.57; 2.09-49.70; 5.10-92.72), Cd (0.03-2.79; 0.01-0.61; 0.25-9.20; 0.15-
3.68), Cu (1.59-79.96; 0.65-14.33; 1.02-184.68; 1.60-134.10), Fe (6.62-149.44; 0.39-12.22;
44.95-375.27; 7.48-548.32) using EDTA, DTPA, HNO3/HClO4 and HCl/HNO3 respectively
as extractants. Results revealed that all extractants showed strong positive correlation in
bringing only Cd into solution. ANOVA depicted no significant difference in mean trace
metals contents of soils from mechanic workshops as extracted with all solutions, while other
locations did. For risk assessment, only Cd, Ni and Pb had their values within the regulatory
limits, whereas others were above the limits in all samples from different locations.
Keywords
Extraction; Soils; Pollution; Trace metals; Abakaliki
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