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Distribution of different fractions of Iron, Zinc, Chromium, lead and Nickel in Soils around Petrol filling stations in selected Areas of Delta State, Nigeria
OSAKWE, STEPHEN ANAPUWA & OKOLIE, LUCKY PRECIOUS
Abstract
The geochemical forms of some heavy metals in soils around selected petrol
filling stations were studied in order to assess the mobility and bioavailability of the metals and
hence their potential environmental risk. Water soluble fraction (F1) contained an average of
0.97% iron, 1.40% zinc, 2.37% chromium, 2.08% lead and 41.96% nickel with the abundance
trend of Ni > Cr > Pb > Zn > Fe. Metal bound to exchangeable phase followed the same
abundance trend with an average of 6.46% nickel, 5.48% chromium, 2.64% lead, 2.55% zinc
and 0.62% iron. Lead was predominantly associated with carbonate fraction with an average of
52.32% followed by iron with an average of 15.41%. Other metal average levels in the
carbonate fractions were 9.66% for nickel, 8.78% for chromium, and 8.73% for zinc giving the
abundance trend of Pb > Fe > Ni > Cr > Zn. The most important metal in iron-manganese oxide
phase was zinc with an average of 42.49%, followed by iron with an average of 32.82%. The
averages of the other metals bound to this phase were 30.39%, 13.24% and 6.46% for
chromium, lead and nickel respectively. The organic bound metals were in the abundance trend
of Fe > Zn > Cr > Pb > Ni with average of 39.48% for iron, 30.87% for zinc, 23.03% for
chromium, 8.54% for lead and 4.94% for nickel. Nickel with an average of 51.58% was
predominantly associated with the residual fraction. The other metals bound to this phase in
order of their importance to the fraction had the average of 22.75% for chromium, 13.96% for
zinc, 12.24% for lead and 10.97% for iron. The mobility factor values of the metals were
moderately high with the abundance trend of Pb > Ni > Cr > Fe > Zn. The generally low levels
of the metals in the residual fraction coupled with the mobility factor trend suggest potential risk
for the metals.
Keywords
Soil pollution; speciation; petrol filling stations; heavy metals; Delta State
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