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Journal of Applied Sciences and Environmental Management
World Bank assisted National Agricultural Research Project (NARP) - University of Port Harcourt
ISSN: 1119-8362
Vol. 21, No. 7, 2017, pp. 1374-1377
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Bioline Code: ja17180
Full paper language: English
Document type: Research Article
Document available free of charge
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Journal of Applied Sciences and Environmental Management, Vol. 21, No. 7, 2017, pp. 1374-1377
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Influence of Temperature and Ion Concentration on Sedimentation Characteristics of Tricalcium phosphate (TCP) and Tristrontium phosphate (TSP) Precipitates
OBUNWO, CC; IBOROMA, SD & COOKEY, GA
Abstract
Physical and chemical variables of insoluble salts generally affect sedimentation characteristics of
precipitates. In this research study, the effects of temperature and ion concentration on the sedimentation of
tricalcium phosphate (TCP) and tristrontium phosphate (TSP) were studied. The focus was to determine the
sedimentation kinetics such as rate, order and rate constant of TCP and TSP at varying temperatures using the
modified initial rate (Isolation) method. It was observed that whereas effect of temperature was not significant, low
concentrations (< 0.04M) of the metal and phosphate ions markedly influenced the initial sedimentation rates of TCP
and TSP precipitates.TCP sedimentation order ranged between 0.63 and 1.23 at constant phosphate ions
concentration and between 1.52 and 2.10 at constant calcium ions concentration. TSP sedimentation order also
ranged between 0.58 and 1.31 at constant phosphate ions concentration and between 1.55 and 1.81 at constant
strontium ions concentration. Furthermore, ranges of sedimentation rate constants were obtained. At constant
phosphate ions concentration, 1.80 × 10-4 - 1.57 × 10-3 and 1.51 × 10-4 - 2.45 × 10-3 were obtained for TCP and TSP,
respectively. At constant metal ions concentration 1.71 × 10-5 - 9.54 × 10-5 and 5.70 × 10-5 - 1.12 × 10-4 were
respectively obtained for TCP and TSP. Data may be employed as additional design information for modeling
physiochemical phosphate removal in water treatment technology.
Keywords
sedimentation rate; sedimentation characteristics; tricalcium phosphate; tristrontium phosphate.
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© Copyright 2017 - Obunwo et al.
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