About Bioline  All Journals  Testimonials  Membership  News  Donations

International Journal of Environment Science and Technology
Center for Environment and Energy Research and Studies (CEERS)
ISSN: 1735-1472
EISSN: 1735-2630
Vol. 8, No. 3, 2011, pp. 501-512
Bioline Code: st11046
Full paper language: English
Document type: Research Article
Document available free of charge

International Journal of Environment Science and Technology, Vol. 8, No. 3, 2011, pp. 501-512

 en New chelating resin for preconcentration and determination of molybdenum by inductive couple plasma atomic emission spectroscopy
Sid Kalal, H.; Ahmad Panahi, H.; Framarzi, N.; Moniri, E.; Naeemy, A.; Hoveidi, H. & Abhari, A.


A chelating resin is prepared by condensation polymerization of aniline with formaldehyde and characterized by Fourier transform infrared spectrometer, elemental analysis and thermogravimetric analysis and studied for the preconcentration and determination of trace Molybdate ion from environmental water sample using inductive couple plasma atomic emission spectroscopy. The optimum pH value for sorption of the metal ion was 5. The sorption capacity of functionalized resin is 3.1 mg/g. The chelating sorbent can be reused for 20 cycles of sorption-desorption without any significant change in sorption capacity. The best desorption of the metal ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent. The profile of molybdenum uptake on this sorbent reflects good accessibility of the chelating sites in the aniline- formaldehyde. Scatchard analysis revealed that the homogeneous binding sites were formed in the polymers. The equilibrium adsorption data of Molybdate ion modified resin were analyzed by five isotherm models such as Langmuir, Freundlich and Temkin. Langmuir isotherm parameters obtained from the four Langmuir linear equations by using linear method. Based on the Langmuir isotherm analysis, the monolayer adsorption capacity was determined to be 4.03 mg/g at 20 °C. The method was applied for molybdenum ions determination from river water sample.

Adsorption; Aniline formaldehyde; Environmental measurement; Isotherm study; Solid phase extraction; Water samples

© Copyright 2011 - Center for Environment and Energy Research and Studies (CEERS)
Alternative site location:

Home Faq Resources Email Bioline
© Bioline International, 1989 - 2018, Site last up-dated on 24-Jul-2018.
Site created and maintained by the Reference Center on Environmental Information, CRIA, Brazil
System hosted by the Internet Data Center of Rede Nacional de Ensino e Pesquisa, RNP, Brazil