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International Journal of Environment Science and Technology
Center for Environment and Energy Research and Studies (CEERS)
ISSN: 1735-1472
EISSN: 1735-2630
Vol. 10, No. 5, 2013, pp. 983-994
Bioline Code: st13094
Full paper language: English
Document type: Research Article
Document available free of charge

International Journal of Environment Science and Technology, Vol. 10, No. 5, 2013, pp. 983-994

 en pH-dependent copper release in acid soils treated with crushed mussel shell
Garrido-Rodríguez, B.; Fernández-Calviño, D.; Muñoz, J. C. Nóvoa; Arias-Estévez, M.; Díaz-Raviña, M.; Álvarez-Rodríguez, E.; Fernández-Sanjurjo, M.J. & Núñez-Delgado, A,


The aim of this study was to assess the influence of pH on copper mobilization in two copper-rich acid soils (from vineyard and mine) amended with crushed mussel shell. Crushed mussel shell amended soils (0-48 Mg ha-1) were subjected to the effect of several acid and alkali solutions in a batch experiment in order to study their copper release. Copper distribution was studied in decanted soils from batch experiments using a sequential extraction procedure, whereas the effect of crushed mussel shell on copper release kinetics was studied using a stirred flow reactor. When soils were treated with acid solutions, the copper mobilization from non-amended soils was significantly higher than from the amended samples. Major changes in copper fractionation were an increase of the acid soluble fraction in acid-treated vineyard soil samples with shell dose. For the mine soil, the oxidable fraction showed a relevant diminution in acid-treated samples at the highest crushed mussel shell dose. For both soils, copper desorption rates diminished up to 86 % at pH 3 when crushed mussel shell was added. At pH 5, copper release rate was very slow for both soils decreasing up to 98 % for the mine soil amended with the highest shell dose, whereas no differences were observed at pH 7 between amended and non-amended soils. Thus, crushed mussel shell addition could contribute to reduce potential hazard of copper-enriched soils under acidification events.

Copper fractionation; Mine soil; Release kinetics; Vineyard

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