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International Journal of Environment Science and Technology
Center for Environment and Energy Research and Studies (CEERS)
ISSN: 1735-1472 EISSN: 1735-1472
Vol. 11, No. 6, 2014, pp. 1641-1652
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Bioline Code: st14160
Full paper language: English
Document type: Research Article
Document available free of charge
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International Journal of Environment Science and Technology, Vol. 11, No. 6, 2014, pp. 1641-1652
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Long-term brine impacted fly ash, Part II: Mobility of major species in the ash residues
Fatoba, O.O.; Petrik, L.F.; Akinyeye, R.O.; Gitari, W.M. & Iwuoha, E.I.
Abstract
The leaching of major species from fly ash is a
function of the pH of the solution in contact with the fly
ash. The aim of this study was to determine the effect of the
pH of the leachant on the leaching of species from the ash
residues recovered after the long-term fly ash–brine interactions.
Acid neutralization capacity (ANC) tests using
solutions of different pH values ranging from the initial pH
of the ash residues (11–12) to pH 4 were employed in the
leaching experiments. The ANC tests revealed that the
release of major species from the ash residues depended on
the pH of the leachants except for Na and Cl, where the
significant concentrations leached were independent of the
solution pH. The concentrations of Al and Si in the ANC
leachates were very high at pH below 6 while Ca, K, Sr,
Mg and B were immediately mobilized from the brine
impacted fly ash when in contact with de-ionized water,
and leaching increased as the pH decreased. The concentration
of SO4 leached from the brine impacted ash residues
at high pH was high, and the leaching increased with
decrease in the pH of the leachant. This study shows that
most of the major elements captured in the ash residues
could be mobilized when in contact with aqueous solutions
of various pH. This reveals that the co-disposal of fly ash
and brine may not be the best practice as the major elements
captured in the ash residues could leach over time.
Keywords
Acid neutralization capacity (ANC); Brine; Fly ash; Major species; Mobility; Co-disposal
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