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Removal of lead from aqueous solutions by electrocoagulation: isotherm, kinetics and thermodynamic studies
Kamaraj, R.; Ganesan, P. & Vasudevan, S.
Abstract
The present study provides an electrocoagulation
process for the removal of lead from water using
magnesium and galvanized iron as anode and cathode,
respectively. The various operating parameters such as the
effect of initial pH, current density, electrode configuration,
inter-electrode distance, co-existing ions and temperature
on the removal efficiency of lead were studied. The results
showed that the maximum removal efficiency of 99.3 % at
a pH of 7.0 was achieved at a current density 0.8 A/dm2
with an energy consumption of 0.72 kWh/m3. The experimental
data were fitted with several adsorption isotherm
models to describe the electrocoagulation process. The
adsorption of lead preferably fitting the Langmuir adsorption
isotherm suggests monolayer coverage of adsorbed
molecules. In addition, the adsorption kinetic studies
showed that the electrocoagulation process was best
described using the second-order kinetic model at various
current densities. Thermodynamic parameters, including
the Gibbs free energy, enthalpy and entropy, indicated that
the lead adsorption of water on magnesium hydroxides was
feasible, spontaneous and endothermic.
Keywords
Electrocoagulation; Heavy metal; Adsorption; Kinetics; Thermodynamics
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