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A novel method for synthesis of nano-γ-Al2O3: study of adsorption behavior of chromium, nickel, cadmium and lead ions
Shokati Poursani, A.; Nilchi, A.; Hassani, A. H.; Shariat, M. & Nouri, J.
Abstract
Nano-γ-Al2O3 adsorbent was synthesized by
the novel sol–gel method. The adsorbent was characterized
by transmission electron microscope, Fourier transform
infrared and X-ray powder diffraction. The effects of several
variables such as, adsorbent weight, pH and contact
time on adsorption of chromium (Cr6+), nickel (Ni2+),
cadmium (Cd2+) and lead (Pb2+) ions were studied in
batch experiments. The results showed that the synthesized
nano-γ-Al2O3 had a good capacity to adsorb Cr and Pb.
The kinetic data were described with pseudo-first- and
pseudo-second-order models. Three isotherm models,
namely Freundlich, Langmuir and Tempkin, were used for
analysis of equilibrium data, and results showed that
Langmuir and Freundlich models were suitable for
describing the equilibrium data of Cr6+, Cd2+, Ni2
+ and
Pb2+. Using Langmuir isotherm, the maximum sorption
capacities of Cr6+, Pb2+, Cd2+ and Ni2+ were estimated to
be 13.3, 6, 1.1 and 0.33 (mg/g) at 25 ° C, respectively. The
sorption capacity did not change remarkably after reuse of
sorbent for sorption–desorption cycle. The selectivity order
of Cr6+, Pb2+, Cd2+ and Ni2+ sorption onto the adsorbent
was Cr6+> Pb2+> Cd2+> Ni2+.
Keywords
nano-γ-Al2O3; Adsorption; Chromium; Cadmium; Nickel; Lead
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