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International Journal of Environment Science and Technology
Center for Environment and Energy Research and Studies (CEERS)
ISSN: 1735-1472 EISSN: 1735-1472
Vol. 12, No. 8, 2015, pp. 2485-2492
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Bioline Code: st15234
Full paper language: English
Document type: Research Article
Document available free of charge
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International Journal of Environment Science and Technology, Vol. 12, No. 8, 2015, pp. 2485-2492
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Removal of hexavalent chromium from aqueous solution by crosslinked mangosteen peel biosorbent
Huang, K.; Xiu, Y. & Zhu, H.
Abstract
In present study the potential of a new biosorbent
obtained from mangosteen peel was investigated for
the removal of hexavalent chromium and trivalent chromium
from the aqueous solutions. The biosorbent was
modified by using concentrated sulphuric acid as the
crosslinking reagent. Various batch experiments were
carried out testing different values of several parameters
such as pH, contact time, adsorbent dosages, and metal ion
concentration to identify the optimum conditions. The
effect of these parameters on the adsorption capacity and
selectivity was studied. Results showed that optimum pH
for hexavalent chromium adsorption was 3.0 and adsorption
equilibrium was attained in 120 min. The adsorption
data were found to fit Langmuir model and pseudo-secondorder
equation. The adsorption mechanism for hexavalent
chromium was found to be a complex process involving
esterification, reduction and ion exchange, while cation
exchange is the main route for trivalent chromium
adsorption. From the above results, the crosslinked mangosteen
peel gel appears to be a potential low-cost and
effective adsorbent for hexavalent chromium and trivalent
chromium removal from the waste water.
Keywords
Biosorption; Chromium; Mangosteen peel; Concentrated sulphuric acid
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