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International Journal of Environment Science and Technology
Center for Environment and Energy Research and Studies (CEERS)
ISSN: 1735-1472 EISSN: 1735-1472
Vol. 12, No. 9, 2015, pp. 2965-2978
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Bioline Code: st15279
Full paper language: English
Document type: Research Article
Document available free of charge
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International Journal of Environment Science and Technology, Vol. 12, No. 9, 2015, pp. 2965-2978
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Study of continuous lead removal from aqueous solutions by marble wastes: efficiencies and mechanisms
Mlayah, A. & Jellali, S.
Abstract
Lead removal from synthetic solutions and real
wastewater by Bianco Gioia marble wastes as abundant,
renewable and eco-friendly materials was studied under
different experimental conditions in a continuous stirring
tank reactor. These marble wastes were found to be very
efficient in removing lead for several experimental situations.
Indeed, for initial aqueous pH values higher than 3.6,
a lead removal efficiency of about 100 % was achieved
even for high aqueous concentrations (200 mg L-1),
important feeding flow rates (60 mL min-1) and low
marble waste dosage (2 g L-1). The best removal capacity
(175.7 mg g-1) was obtained for an initial lead concentration
of 200 mg L-1, a marble waste dose of 5 g L-1 and
an aqueous pH of 5. Even using the real wastewater with
low aqueous pH (1.1), lead was also completely removed
using 20 g L-1 of the tested marble wastes. According to
the energy-dispersive spectroscopy and X-ray diffraction
analyses, lead removal seems to be controlled by both
precipitation as cerussite (PbCO3) and hydrocerussite
(Pb3(CO3)2(OH)2), and adsorption onto the surface particles
through cation exchange and complexation. The proposed
low-cost material efficiently removes lead present in
synthetic solutions and real wastewaters and constitutes an
interesting environmental management option.
Keywords
Dynamic mode; Mineral adsorbents; Precipitation; Wastes management; Water pollutants
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